Speaking at the NH3 Energy+ Topical Conference last month, University of Delaware Adjunct Professor Shimshon Gottesfeld reported on progress made by the university’s direct ammonia fuel cell (DAFC) project. Evidently, the UDel team is now a big step closer to its goal of establishing the DAFC as a viable automotive power plant.
I wrote recently about two pathways for ammonia production technology development: improvements on Haber-Bosch, or electrochemical synthesis. Last week, I covered some of these Haber-Bosch improvements; next week, I'll write about electrochemical processes. This week, I want to write about some innovations that don't fit this two-way categorization: they don't use electrochemistry and they don't build upon the Haber-Bosch process, and that might be the only thing that links them.
A new report from Australia identifies ammonia as a key part of a hydrogen-based high-volume energy storage system. On November 20, Australia’s Council of Learned Academies (ACOLA) and its Chief Scientist released “The Role of Energy Storage in Australia’s Future Energy Supply Mix.” In addition to hydrogen, the report covers pumped hydro, batteries, compressed air, and thermal systems. Its rationale for including ammonia is starkly simple: “Hydrogen gas is difficult to transport due to its low density; instead, it is proposed that hydrogen is converted to ammonia for transport, and then converted back to hydrogen for use.” Although an ultimate ranking of energy storage options is not provided, the hydrogen-ammonia combination arguably emerges as the best option in terms of economics, environmental and social impact, and deployability.
At the recent NH3 Energy+ Topical Conference, Grigorii Soloveichik described the future of ammonia synthesis technologies as a two-way choice: Improvement of Haber-Bosch or Electrochemical Synthesis. Two such Haber-Bosch improvement projects, which received ARPA-E-funding under Soloveichik's program direction, also presented papers at the conference. They each take different approaches to the same problem: how to adapt the high-pressure, high-temperature, constant-state Haber-Bosch process to small-scale, intermittent renewable power inputs. One uses adsorption, the other uses absorption, but both remove ammonia from the synthesis loop, avoiding one of Haber-Bosch's major limiting factors: separation of the product ammonia.
Of all the devices that can convert the chemical energy in ammonia to electricity, gas turbines and fuel cells appear to be receiving the lion’s share of development effort, outstripping that devoted to ammonia-fueled internal combustion engines (A-ICEs). An Ammonia Energy review last year found a number of organizations with histories of work on A-ICE technology, but reports of progress have not been forthcoming. It was good news, therefore, when a representative of a newly engaged group appeared at the NH3 Energy+ Topical Conference earlier this month and delivered a talk on an innovative A-ICE “combustion strategy.” Donggeun Lee from the Department of Mechanical Engineering at Seoul National University (SNU) delivered the paper, entitled “Development of new combustion strategy for internal combustion engine fueled by pure ammonia,” on behalf of his co-authors, Hyungeun Min, Hyunho Park, and Han Ho Song.
Gideon Grader, a Faculty Dean at Technion Israel Institute of Technology, and Bar Mosevitzky, one of the members of his laboratory, spoke in separate talks at the NH3 Energy + Topical Conference about one of the Grader Research Group’s key focuses: nitrogen-based energy carriers. Grader and his team champion the idea that ammonia can be the starting rather than ending point for nitrogen-containing fuels for heat engines. The focuses of their research include ammonium hydroxide ammonium nitrate (AAN), ammonium hydroxide urea (AHU), and urea ammonium nitrate (UAN). As described below, this work is an indispensable addition to the C-fuel vs. N-fuel debate well known to proponents of ammonia energy. And the Grader team stakes out a position: per the abstract of Grader’s talk, “using nitrogen as a hydrogen carrier can potentially offer a superior option.”
During our NH3 Energy+ Topical Conference, hosted within AIChE's Annual Meeting earlier this month, an entire day of presentations was devoted to new technologies to make industrial ammonia production more sustainable. One speaker perfectly articulated the broad investment drivers, technology trends, and recent R&D achievements in this area: the US Department of Energy's ARPA-E Program Director, Grigorii Soloveichik, who posed this question regarding the future of ammonia production: "Improvement of Haber-Bosch Process or Electrochemical Synthesis?"
This morning in Beijing, China, the International Energy Agency (IEA) launched a major new report with a compelling vision for ammonia's role as a "hydrogen-rich chemical" in a low-carbon economy. Green ammonia would be used by industry "as feedstock, process agent, and fuel," and its production from electrolytic hydrogen would spur the commercial deployment of "several terawatts" of new renewable power. These terawatts would be for industrial markets, additional to all prior estimates of renewable deployment required to serve electricity markets. At this scale, renewable ammonia would, by merit of its ease of storage and transport, enable renewable energy trading across continents. The IEA's report, Renewable Energy for Industry, will be highlighted later this month at the COP23 in Bonn, Germany, and is available now from the IEA's website.
Last month the NH3 event Europe Foundation released a “call for papers” for the 2nd European Conference on Sustainable Ammonia Solutions. The conference will take place in Rotterdam on May 17 and 18, 2018, almost exactly a year after the 1st Conference. This is further fulfillment of a vision articulated by Hans Vrijenhoef, Managing Director of Proton Ventures in the Netherlands, during the formation of the NH3 Fuel Association’s Global Ammonia Energy Federation (GAEF) in 2016. In Vrijenhoef’s view, the rising level of activity and interest in ammonia energy created a compelling opportunity and need for a European conference.
In August of 2017 a symposium on the Ammonia Economy was held in Washington DC as part of the Energy and Fuels Division of the American Chemical Society (ACS) conference. The symposium was devised to explore the latest results from ammonia related research, including but not limited to; advances in the generation of ammonia, advances in the catalytic cracking of ammonia to nitrogen and hydrogen, ammonia storage and utilisation, detectors and sensors for ammonia, ammonia fuel cells and hydrogen from ammonia, ammonia combustion and ammonia safety.