ARPA-E

This week the United States Department of Energy’s Advanced Research Projects Agency – Energy (ARPA-E) issued a Request for Information under the title “Next Generation Ammonia System Integration Project.” This is a strong signal that ARPA-E intends to see the ammonia energy technologies in its portfolio through to commercial fruition.

ANNOUNCEMENT: The US Department of Energy's Advanced Research Projects Agency (ARPA-E) has published a Request For Information (RFI) focused on supporting scale-up demonstrations of ARPA-E technologies. Unlike normal ARPA-E funding agreements, which typically provide 5%-20% of the financing for bench-scale projects within laboratories, this RFI is geared towards industrial pilot projects, for which ARPA-E would provide "at least 50% cost share."

The 2018 NH3 Energy Implementation Conference, the first of its kind, took place on November 1 in Pittsburgh, Pennsylvania in the U.S. The focus of the Conference was on steps – current and future – that will lead to implementation of ammonia energy in the global economy.  At the highest level, the Conference results validated the relevance and timeliness of the theme.  In the words of closing speaker Grigorii Soloveichik, Director of the U.S. Department of Energy’s ARPA-E REFUEL Program, the Conference strengthened his confidence that “ammonia is a great energy carrier ... with billions of dollars of potential in prospective markets.”

Yara International, one of the world’s largest ammonia producers, is making strides in its development of green ammonia as a fertilizer, chemical intermediate, and energy carrier.  The progress is documented in the company’s 2017 annual report, released last week, and in more detail in a presentation delivered in late February at the 2018 Nitrogen + Syngas Conference in Gothenburg, Sweden.

This series of articles on the future of ammonia synthesis began with a report on the NH3 Energy+ conference presentation by Grigorii Soloveichik, Program Director at the US Department of Energy's ARPA-E, who categorized the technologies as being either improvements on Haber-Bosch or electrochemical (with exceptions). ARPA-E invests in "transformational, high-risk, early-stage research," and recently began funding ammonia synthesis technologies, not to make renewable fertilizer but to produce "energy-dense zero-carbon liquid fuel." This article will introduce the six electrochemical technologies currently in development with funding from ARPA-E.

At the recent NH3 Energy+ Topical Conference, Grigorii Soloveichik described the future of ammonia synthesis technologies as a two-way choice: Improvement of Haber-Bosch or Electrochemical Synthesis. Two such Haber-Bosch improvement projects, which received ARPA-E-funding under Soloveichik's program direction, also presented papers at the conference. They each take different approaches to the same problem: how to adapt the high-pressure, high-temperature, constant-state Haber-Bosch process to small-scale, intermittent renewable power inputs. One uses adsorption, the other uses absorption, but both remove ammonia from the synthesis loop, avoiding one of Haber-Bosch's major limiting factors: separation of the product ammonia.

The NH3 Fuel Association has finalized details of its Sponsors Reception on Wednesday November 1 at the AIChE Annual Meeting in Minneapolis, and has also announced an additional sponsor for the conference: Starfire Energy.

In the last 12 months ... Groups in Australia, Japan, Denmark, the U.K., and the U.S. all made progress with technologies that can be used to convert ammonia to hydrogen at fueling stations. This means that hydrogen for fuel cell vehicles can be handled as ammonia from the point of production to the point of dispensing.

Chiyoda Corporation, the multinational chemical engineering firm that is arguably the leading proponent of the methyl cyclohexane (MCH) method of hydrogen transport, will start work this month on a project to demonstrate MCH technology in a real-world context.  As reported in a July 27 company press release, the project will involve the transportation of hydrogen from Brunei to Japan in what the company states is "the world's first global hydrogen supply chain demonstration project" -- an assertion that many ammonia energy proponents will no doubt find preposterous.

At ARPA-E's recent Energy Innovation Summit in Washington, DC, Program Director Grigorii Soloveichik presented his vision for the future of transportation: hybrid electric vehicles that combine the advantages of both plug-in battery and fuel cell technologies. This "optimal solution" will require a new generation of fuel cell that is "fast, furious, and flexible." Fast, in terms of start-up / shut-down time. Furious, in terms of energy density. And flexible, in terms of fuel choice - specifically sustainable liquid fuels, like ammonia.

We wrote last month about the US Department of Energy funding ammonia fuel projects through ARPA-E's "REFUEL" program ("Renewable Energy to Fuels through Utilization of Energy-dense Liquids"). Although we introduced the funded projects in both the ammonia synthesis category and the ammonia fuel-use category, the REFUEL project merits further analysis as a whole because it describes a roadmap for the development of ammonia fuel systems, and identifies benchmarks for their commercial success.

Last week, ARPA-E announced funding for eight technologies that aim to make ammonia from renewable electricity, air, and water. The technological pathways being developed include adaptations of the Haber-Bosch process - seeking improvements in catalysts and absorbents - as well as novel electrochemical processes.