Cardiff University

Ahead of the 3rd Symposium on Ammonia Energy in Shanghai next month, we take the opportunity to highlight select papers and key results from the first two editions, starting with the 2022 Cardiff event:

• In an ammonia-diesel blending study, Orleans University and WinGD found that minimising the diesel fraction actually led to increased N₂O emissions.
• In a bid to produce an optimal ammonia-hydrogen fuel blend, a University of Birmingham team characterised the ammonia cracking mechanism of a new, transition metal-promoted lithium amide catalyst.
• A KAUST study of swirl intensity of an ammonia-methane blended fuel finds that increasing the swirl number leads to a more compact flame, reducing NO_X emissions.
• A team from the University of Minnesota found that combustion durations comparable to gasoline were obtained for ammonia-hydrogen fuel blends.
• And, as part of a joint academic-industry session on safety, it was recommended that a careful, proactive approach is taken towards new ammonia users, likely exposure risk points and deploying maritime ammonia fuel.

Welcome to the Ammonia Academic Wrap: a summary of all the latest papers, developments and emerging trends in the world of ammonia energy R&D. This week: "seamless" ammonia cracking tech from Northwestern, a new electrolysis catalyst, successful integration of ammonia synthesis and separation for improved efficiency, more research needed into transition metal catalysts for Haber Bosch, a novel, green power-to-ammonia to power system and a review on ammonia as a potential fuel.

Techno-Economic Challenges of Green Ammonia as an Energy Vector, a new textbook, was issued in September by scientific and technical publisher Elsevier. The 340-page volume was written by Agustin Valera-Medina of Cardiff University and Rene Banares-Alcantara of Oxford University. The book is a valuable consolidation of knowledge across the many aspects of ammonia energy, and seems destined to become a go-to reference for current and future technologists, project developers, and policy makers.

Last week Agustin Valera-Medina, Associate Professor at Cardiff University in the United Kingdom, told Ammonia Energy that work is underway on a £1.9 million (USD $2.3 million) project that will advance the frontiers of ammonia-gas turbine (AGT) technology. Valera-Medina is serving as the Principal Investigator of the Storage of Ammonia for Energy (SAFE) – AGT Pilot, a four-year effort that hopes to develop “a unique, competitive technology that can be implemented to support the hydrogen transition.”

The 2018 NH3 Energy Implementation Conference, the first of its kind, took place on November 1 in Pittsburgh, Pennsylvania in the U.S. The focus of the Conference was on steps – current and future – that will lead to implementation of ammonia energy in the global economy.  At the highest level, the Conference results validated the relevance and timeliness of the theme.  In the words of closing speaker Grigorii Soloveichik, Director of the U.S. Department of Energy’s ARPA-E REFUEL Program, the Conference strengthened his confidence that “ammonia is a great energy carrier ... with billions of dollars of potential in prospective markets.”

During development of the technical aspects of any energy project, a social perspective needs to be considered. Public opinion is going to be a fundamental parameter to determine the role of renewables in the future, with decarbonisation meaning innovation towards a comprehensive plan that involves not only technology but also psychology and how these two can benefit from each other. Due to the importance of understanding public perception of ammonia, Cardiff University conducted a study focused on the Yucatan Peninsula, Mexico, which currently presents high revenues in agriculture and depends on ammonia as a fertiliser. An analysis of stakeholder’s perception of ammonia was carried out to understand the different barriers and drivers of each established group.

As part of the sustainable agenda of the UK, the government, research institutions and various enterprises have looked for options to reduce the carbon footprint of the country while ensuring energy independence for several years. As a response, one of the alternatives has been to introduce the use of marine energy via the implementation of a barrage in the Severn Estuary or the development and implementation of Tidal Lagoons located around the Welsh coast. From these alternatives, the tidal lagoon concept seems to be most feasible. Hybrid tidal and wind energy systems will produce vast amounts of energy during off-peak hours that will require the use of energy storage technologies - the size of each proposed tidal lagoon ranges close to ~1.5 GW. Currently, companies involved in the development of these complexes are thinking of batteries, pumped hydro, and ammonia as the potential candidates to provide storage for these vast amounts of energy.

The American Chemical Society (ACS) has published the program for its 2017 National Meeting, which takes place next month in Washington DC and includes a session dedicated to the "Ammonia Economy." The first day of the week-long meeting, Sunday August 20th, will feature a full morning of technical papers from the US, UK, and Japan, covering ammonia energy topics across three general areas: producing hydrogen from ammonia, developing new catalysts for ammonia synthesis and oxidation, and storing ammonia in solid chemical form.

In April 2016, Siemens AG announced that it will construct a plant at the Rutherford Appleton Laboratory in Oxford to demonstrate the production of ammonia in an electrochemical reactor. The technology is seen as a facilitator of the use of ammonia synthesis as a method for storing renewably generated electricity. It involves lower pressures and temperatures than conventional synthesis with the Haber Bosch process. The project will test two different electrolyte chemistries using its 30 kilowatt electrochemical reactor.