Japanese government funding via NEDO will support four critical ammonia energy projects, including JERA's new plan to demonstrate 50% ammonia-coal co-firing by 2030. Other projects include improved catalysts for ammonia production, low-temperature and low-pressure synthesis pathways, and developing 100% ammonia-fed boilers and gas turbines. In addition, a new cooperation agreement between ASEAN countries will see Japan support other members to adopt their ammonia energy solutions, particularly coal co-firing.
Content Related to National Institute of Advanced Industrial Science and Technology (AIST)
Literature Review: Ammonia as a Fuel for Compression Ignition Engines
The diesel engine, also known as the compression ignition (CI) engine, has been a workhorse of the modern energy economy for more than a hundred years. Its role in the coming sustainable energy economy will be determined by its ability to co-evolve with climate-friendly fuels. Two researchers from the National Institute of Advanced Industrial Science and Technology in Japan have now examined the fit between ammonia and the CI engine. Pavlos Dimitriou and Rahat Javaid arrive at a two-part conclusion in their paper, “A review of ammonia as a compression ignition engine fuel,” published in January in the International Journal of Hydrogen Energy. Part one is good news: “Ammonia as a compression ignition fuel can be currently seen as a feasible solution.” Part two is a dose of qualifying reality: to manage emissions of N2O, NOx, and unburnt NH3, “aftertreatment systems are mandatory for the adaptation of this technology,” which means that ammonia-fueled CI engines are likely to be feasible “only for marine, power generation and possibly heavy-duty applications where no significant space constraints exist.”
Synthesis and Assessment of Process Systems for Production of Ammonia Using Nitric Oxide in Combustion Exhaust Gas
Effect of Preparation Condition on Ammonia Synthesis over Ru/CeO
Pure Ammonia Combustion Micro Gas Turbine System
Demonstration and Optimization of Green Ammonia Production Operation Responding to Fluctuating Hydrogen Production from Renewable Energy
IHI Breaks Ground on Hydrogen Research Facility
Japanese capital goods manufacturer IHI Corporation announced last month that it has started construction of a 1,000 square-meter hydrogen research facility in Fukushima Prefecture. The facility will be an addition to IHI’s Green Energy Center in Soma City which was launched in 2018. One of the Center’s original focuses is the production steps of the green hydrogen supply chain using solar electricity to power developmental electrolyzers. The new facility will focus on hydrogen carriers, including ammonia and methane (via “methanation” of carbon dioxide), that can be used in the logistics steps of the supply chain.
JGC Corporation demonstrates "world's first" carbon-free ammonia energy cycle
In late 2018, JGC Corporation issued a press release to celebrate a "world's first" in ammonia energy, demonstrating at its pilot plant in Koriyama both "synthesis of ammonia with hydrogen produced through the electrolysis of water by renewable energy, and generation of electricity through gas turbines fueled by synthesized ammonia." By demonstrating the feasibility of using ammonia on both sides of the renewable energy equation -- first, producing green ammonia from intermittent renewable electricity and, second, combusting this carbon-free fuel for power generation -- the project demonstrates the role of ammonia in the "establishment of an energy chain ... that does not emit CO2 (CO2-free) from production to power generation."
Demonstration of CO2-Free Ammonia Synthesis Using Renewable Energy-Generated Hydrogen
Analysis of influence of operating pressure on dynamic behavior of ammonia production over ruthenium catalyst under high pressure condition
Development of Low-NOx Combustor of Micro Gas Turbine Firing Ammonia Gas
Green ammonia demonstration plants now operational, in Oxford and Fukushima
Two new pilot projects for producing "green ammonia" from renewable electricity are now up and running and successfully producing ammonia. In April 2018, the Ammonia Manufacturing Pilot Plant for Renewable Energy started up at the Fukushima Renewable Energy Institute - AIST (FREA) in Japan. Earlier this week, Siemens launched operations at its Green Ammonia Demonstrator, at the Rutherford Appleton Laboratory outside Oxford in the UK. The commercial product coming out of these plants is not ammonia, however, it is knowledge. While both the FREA and Siemens plants are of similar scale, with respective ammonia capacities of 20 and 30 kg per day, they have very different objectives. At FREA, the pilot project supports catalyst development with the goal of enabling efficient low-pressure, low-temperature ammonia synthesis. At Siemens, the pilot will provide insights into the business case for ammonia as a market-flexible energy storage vector.
Full program announced for the 2018 NH3 Event Europe
The second annual European Conference on Sustainable Ammonia Solutions has announced its full program, spread over two days, May 17 and 18, 2018, at Rotterdam Zoo in the Netherlands. The international cadre of speakers, representing a dozen countries from across Europe as well as the US, Canada, Israel, and Japan, will describe global developments in ammonia energy from the perspectives of industry, academia, and government agencies.
Influence of H2 / N2 Ratio on Dynamic Behavior of Ammonia Production on Ru Catalyst Under Low Pressure Condition
Combustion Emissions from NH3 Fuel Gas Turbine Power Generation Demonstrated
SIP "Energy Carriers" video: ammonia turbines, industrial furnaces, fuel cells
To demonstrate the progress of the SIP "Energy Carriers" program, the Japan Science and Technology Agency last week released a video, embedded below, that shows three of its ammonia fuel research and development projects in operation. R&D is often an abstract idea: this video shows what it looks like to generate power from ammonia. As it turns out, fuel cells aren't hugely photogenic. Nonetheless, if a picture is worth a thousand words, this will be a long article.
Progress toward Ammonia-to-Hydrogen Conversion at H2 Fueling Stations
In the last 12 months ... Groups in Australia, Japan, Denmark, the U.K., and the U.S. all made progress with technologies that can be used to convert ammonia to hydrogen at fueling stations. This means that hydrogen for fuel cell vehicles can be handled as ammonia from the point of production to the point of dispensing.
Green Ammonia Consortium: Bright Prospects in Japan for Ammonia as an Energy Carrier
In the last 12 months ... In July 2017, 19 companies and three research institutions came together to form the Green Ammonia Consortium. Before this development, it was unclear whether ammonia would find a significant role in Japan’s hydrogen economy. In the wake of this announcement, however, ammonia seems to have claimed the leading position in the race among potential energy carriers.
Kawasaki Moving Ahead with LH2 Tanker Project
Kawasaki Heavy Industries (KWI) is moving ahead with plans for a “liquefied hydrogen carrier ship,” as reported by at least two Japanese news outlets since July. This means that the groups backing each of the energy carriers included within Japan’s Cross-Ministerial Strategic Innovation Promotion Program (SIP) have all made significant moves ahead of the program’s termination at the end of 2018. On July 25, 2017 the Japan Science and Technology Agency (JST) announced that a collection of companies and research institutions had come together to form the Green Ammonia Consortium. On July 27, 2017, Chiyoda Corporation announced that work was starting on a demonstration project that will transport hydrogen from Brunei to Japan using liquid organic hydride carrier technology.
Major Development for Ammonia Energy in Japan
On July 25, the Japan Science and Technology Agency (JST) announced that a collection of companies and research institutions had come together to form a Green Ammonia Consortium. The 22-member group will take over responsibility for the ammonia aspect of the Cross-Ministerial Strategic Innovation Program (SIP) Energy Carriers agenda when the SIP is discontinued at the end of fiscal 2018. A JST press release states that the Consortium intends to develop a strategy for “forming [an] ammonia value chain,” promote demonstration projects that can further commercialization, and enable “Japanese industry to lead the world market.”
The Ammonia Economy at the ACS National Meeting
The American Chemical Society (ACS) has published the program for its 2017 National Meeting, which takes place next month in Washington DC and includes a session dedicated to the "Ammonia Economy." The first day of the week-long meeting, Sunday August 20th, will feature a full morning of technical papers from the US, UK, and Japan, covering ammonia energy topics across three general areas: producing hydrogen from ammonia, developing new catalysts for ammonia synthesis and oxidation, and storing ammonia in solid chemical form.
Ammonia-Fueled Gas Turbine Power Generation
Hideaki Kobayashi, professor at the Institute of Fluid Science at Tohoku University in Sendai, Japan, has developed the world’s first technology for direct combustion of ammonia in a gas turbine. The advance was made in cooperation with the National Institute of Advanced Industrial Science and Technology (AIST) under a program led by Norihiko Iki.
On the Ground in Japan
Two talks delivered in December show the tiny steps that allow a country to transition to a sustainable energy economy. The country is Japan. The events hosting the talks were short-format symposia whose evident objective was to draw in business and technical people who might become practically involved in the new energy economy. Both talks highlighted the role to be played by ammonia while also describing competing and complementary technologies.
Ammonia Turbine Power Generation with Reduced NOx
A common concern with ammonia fuel is that NOx emissions will be too high to control. However, in new research from Turkey, USA, and Japan, presented at this year's NH3 Fuel Conference in September 2016, two things became clear. First, NOx emissions can be reduced to less than 10ppm by employing good engineering design and exploiting the chemical properties of ammonia, which plays a dual role as both the fuel and the emissions-cleanup agent. Second, the deployment of ammonia-fueled turbines for power generation is not only feasible, but actively being developed, with demonstration units running today and improved demonstration projects currently in development.
Combustion characteristics of ammonia/air flames for a model swirl burner and an actual gas turbine combustor
Japan's Fourth Strategic Energy Plan
The Cabinet of the Government of Japan adopted the country’s Fourth Strategic Energy Plan in April 2014. The Plan includes a Strategy for Hydrogen & Fuel Cells which is being executed by the Ministry of Economy, Trade and Industry (METI). The accompanying H2/FC Road Map includes an investigation of three materials that can carry the energy embodied in molecular hydrogen: liquid hydrogen, organic hydrides such as methylcyclohexane, and ammonia.