Japan’s Green Ammonia Consortium, an industry body dedicated to building “a value chain from supply to use of CO2-free ammonia,” launched its Web site on December 5. The site features plenty of interesting content, but most significant may be the roster of members. Eighty seven companies, public organizations, and individuals are listed. Taken together they represent a significant force for ammonia energy implementation in Japan and beyond.
Content Related to Toyota Industries
Presentation
Development of Catalytic Reactors and Solid Oxide Fuel Cells Systems for Utilization of Ammonia
Koichi EguchiYosuke TakahashiTakahiro MatsuoHayahide YamasakiHidehito KuboAkihiro OkabeTakenori Isomura
Hydrogen is the primary fuel source for fuel cells. However, the low volume density and difficulty in storage and transportation are major obstacles for the practical utilization. Among various hydrogen carriers, ammonia is one of the promising candidates because of its high hydrogen density and boiling point and ease in liquefaction and transportation. The reaction temperature of ammonia cracking to nitrogen and hydrogen, being about 600°C or higher, is close to the operating temperature of solid oxide fuel cells (SOFCs). The integration of these two devices is beneficial in terms of heat and energy managements and will lead to the…
Article
Green Ammonia Consortium Comes to the Fore in Japan
Stephen H. Crolius December 21, 2017
On December 8, the Nikkei Sangyo Shimbun ran a story about the future of coal-fired electricity generation in Japan. The story touched on topics ranging from the plumbing in a Chugoku Electric generating station to the Trump administration’s idiosyncratic approach to environmental diplomacy. And it contained this sentence: “Ammonia can become a ‘savior’ of coal-fired power.” Clearly an explanation is in order.
Presentation
Development of Materials and Systems for Ammonia-Fueled Solid Oxide Fuel Cells
Koichi EguchiYosuke TakahashiHayahide YamasakiHidehito KuboAkihiro OkabeTakenori IsomuraTakahiro Matsuo
Hydrogen is the primary fuel source for fuel cells. However, the low volume density and difficulty in storage and transportation are major obstacles for the practical utilization. On-site generation of hydrogen from its carrier is an effective method for the fuel supply. Among various hydrogen carriers, ammonia is one of the promising candidates. Ammonia has high hydrogen density. The boiling point of ammonia is relatively high, leading to the ease in liquefaction and transportation. Hydrogen can be produced from ammonia with a mildly endothermic process. The reaction temperature of ammonia cracking is about 600˚C or higher which is close to…
Article
Progress toward Ammonia-to-Hydrogen Conversion at H2 Fueling Stations
Stephen H. Crolius October 05, 2017
In the last 12 months ... Groups in Australia, Japan, Denmark, the U.K., and the U.S. all made progress with technologies that can be used to convert ammonia to hydrogen at fueling stations. This means that hydrogen for fuel cell vehicles can be handled as ammonia from the point of production to the point of dispensing.
Article
Green Ammonia Consortium: Bright Prospects in Japan for Ammonia as an Energy Carrier
Stephen H. Crolius October 05, 2017
In the last 12 months ... In July 2017, 19 companies and three research institutions came together to form the Green Ammonia Consortium. Before this development, it was unclear whether ammonia would find a significant role in Japan’s hydrogen economy. In the wake of this announcement, however, ammonia seems to have claimed the leading position in the race among potential energy carriers.
Article
Major Development for Ammonia Energy in Japan
Stephen H. Crolius August 10, 2017
On July 25, the Japan Science and Technology Agency (JST) announced that a collection of companies and research institutions had come together to form a Green Ammonia Consortium. The 22-member group will take over responsibility for the ammonia aspect of the Cross-Ministerial Strategic Innovation Program (SIP) Energy Carriers agenda when the SIP is discontinued at the end of fiscal 2018. A JST press release states that the Consortium intends to develop a strategy for “forming [an] ammonia value chain,” promote demonstration projects that can further commercialization, and enable “Japanese industry to lead the world market.”
Article
Ammonia-Fueled Solid Oxide Fuel Cell Advance at Kyoto University
Stephen H. Crolius July 20, 2017
Earlier this month the Eguchi Laboratory at Kyoto University announced advances in ammonia-fueled solid oxide fuel cell technology. The lab was able to produce a functioning fuel cell with a power output of one kilowatt. The device attained “direct current power generation efficiency” in excess of 50% and reached 1,000 hours of continuous operation.
Article
The Ammonia Economy at the ACS National Meeting
Trevor Brown July 06, 2017
The American Chemical Society (ACS) has published the program for its 2017 National Meeting, which takes place next month in Washington DC and includes a session dedicated to the "Ammonia Economy." The first day of the week-long meeting, Sunday August 20th, will feature a full morning of technical papers from the US, UK, and Japan, covering ammonia energy topics across three general areas: producing hydrogen from ammonia, developing new catalysts for ammonia synthesis and oxidation, and storing ammonia in solid chemical form.
Article
Hydrogen Fueling Station Development in Japan
Stephen H. Crolius February 03, 2017
Two announcements – focused on very different approaches for supplying hydrogen as a transportation fuel – shine a light on Japan’s approach to creating a national hydrogen energy economy. On January 24, the American company Air Products and Chemicals, Inc. issued a press release about the launch of the Shikaoi Hydrogen Farm fueling station in Hokkaido, Japan. The station will be supplied by hydrogen derived from agricultural wastes via anaerobic digestion and Air Products’ biogas purification and steam methane reforming (SMR) technologies. The project was undertaken by a consortium that includes the Japanese companies Nippon Steel and Sumikin Pipeline & Engineering, Air Water, Inc., and Kajima Corporation. Six months earlier, on July 19, 2016, the Japan Science and Technology Agency (JST) announced that another consortium – this one led by Hiroshima University and including Showa Denko, Taiyo Nichi Company, and Toyota Industries – had succeeded in developing “viable technology to produce high-purity hydrogen [from an] ammonia hydrogen station.”
Article
Hydrogen Council - new global initiative launched at Davos
Trevor Brown January 20, 2017
This week, at the World Economic Forum in Davos, the leaders of 13 global companies, representing more than EUR 1 trillion in annual revenues, announced the launch of the Hydrogen Council. This new global initiative is important for obvious reasons: it presents a compelling "united vision and long-term ambition" for hydrogen, it promises global engagement with "key stakeholders such as policy makers, business and hydrogen players, international agencies and civil society," and it pledges financial commitments to RD&D totaling EUR 10 billion over the next five years. It is important for a subtler reason too: it is the first hydrogen industry promotion I've seen that includes ammonia. It includes ammonia both implicitly, encompassing "hydrogen and its compounds," and explicitly, listing ammonia as a "renewable fuel" in its own right.
Article
How to create a market for low-carbon ammonia: product labeling
Trevor Brown November 04, 2016
I wrote last week about ARPA-E's "transformative" ammonia synthesis technologies, describing three technology pathways under development: low pressure Haber-Bosch, electrochemical processes, and advanced electrolysis. ARPA-E's ambitious R&D program might imply that a meaningful, commercial market for sustainable ammonia is still decades away. It represents, however, only the slow American tip of a fast-moving global iceberg. In Japan, where there's no debate about climate science, the national effort is already well underway, with three programs to develop low-carbon ammonia synthesis under the Cross-ministerial Strategic Innovation Promotion Program (SIP), 'Energy Carriers.'
Article
Ammonia-Powered Internal Combustion Engines
Stephen H. Crolius November 02, 2016
Ammonia energy proponents look forward to the day when their fuel is used in internal combustion engines – but the state of this art is unsettled and it is not clear which combustion technologies will win in the end.
Article
Ammonia Turbine Power Generation with Reduced NOx
Trevor Brown October 06, 2016
A common concern with ammonia fuel is that NOx emissions will be too high to control. However, in new research from Turkey, USA, and Japan, presented at this year's NH3 Fuel Conference in September 2016, two things became clear. First, NOx emissions can be reduced to less than 10ppm by employing good engineering design and exploiting the chemical properties of ammonia, which plays a dual role as both the fuel and the emissions-cleanup agent. Second, the deployment of ammonia-fueled turbines for power generation is not only feasible, but actively being developed, with demonstration units running today and improved demonstration projects currently in development.
Presentation
Research and Development of Ammonia-fueled SOFC Systems
Koichi EguchiAtthapon SrifaTakeou OkanishiHiroki MuroyamaToshiaki MatsuiMasashi KishimotoMotohiro SaitoHiroshi IwaiHideo YoshidaMasaki SaitoTakeshi KoideHiroyuki IwaiShinsuke SuzukiYosuke TakahashiToshitaka HoriuchiHayahide YamasakiShohei MatsumotoShuji YumotoHidehito KuboJun KawaharaAkihiro OkabeYuki KikkawaTakenori Isomura
Ammonia is a promising hydrogen carrier because of its high hydrogen density, low production cost, and ease in liquefaction and transport. Ammonia decomposes into nitrogen and hydrogen through a mildly endothermic process. The ammonia decomposition temperature is close to the operating conditions of solid oxide fuel cells (SOFCs). Therefore, the integration of these two devices is beneficial in terms of efficient heat and energy managements and will lead to the development of simplified generation systems. We have investigated three types of ammonia-fueled SOFC systems. In one system, ammonia is directly supplied to the anode chamber. Ammonia decomposes into nitrogen and…
Presentation
Current progress in development of NH3-fueled solid-state fuel cell systems
Takeou OkanishiKaname OkuraJun YangHiroki MuroyamaToshiaki MatsuiMasashi KishimotoMotohiro SaitoHiroshi IwaiHideo YoshidaKoichi EguchiHiroyuki IwaiK. InaokaShinsuke SuzukiYosuke TakahashiToshitaka HoriuchiHayahide YamasakiHideyuki MatsumotoHidehito KuboJun KawaharaAkihiro OkabeYuki KikkawaT. NegishiS. Watanabe
Current progress in development of NH3-fueled solid-state fuel cell systems T. Okanishi*, K. Okura, J. Yang, H. Muroyama, T. Matsui, M. Kishimoto, M. Saito, H. Iwai, H. Yoshida, K. Eguchi, Kyoto University; H. Iwai, K. Inaoka, S. Suzuki, Y. Takahashi, Noritake; T. Horiuchi, H. Yamasaki, Nippon Shokubai; S. Matsumoto, H. Kubo, Toyota Industries; J. Kawahara, A. Okabe, Mitsui Chemical; Y. Kikkawa, T. Negishi, S. Watanabe, Tokuyama