On April 27 the on-line journal Science Advances published “Carbon-free H2 production from ammonia triggered at room temperature with an acidic RuO2/γ-Al2O3 catalyst.” The lead author, Katsutoshi Nagaoka, and his six co-authors are associated with the Department of Applied Chemistry at Oita University in Japan. The innovation featured in the paper could prove to be an important enabler of ammonia fuel in automotive applications.
Next month the print edition of Fuel Processing Technology will feature a paper entitled “Auto-ignition of a carbon-free aqueous ammonia/ammonium nitrate monofuel: a thermal and barometric analysis.” This title is provocative. First, what is this idea of a fuel composed of a mixture of ammonia and ammonium nitrate (AN)? If ammonia is a good fuel, is it made better with the addition of ammonium nitrate? Second, why is it aqueous? Is the presence of water a feature or a bug? Third, what is a monofuel and why is this term used when the fuel is a mixture of two molecular species? And finally, why is the paper ultimately about auto-ignition?
The shipping industry is beginning to evaluate ammonia as a potential "bunker fuel," a carbon-free alternative to the heavy fuel oil (HFO) used in maritime transport. International trade associations are leading the effort to decarbonize the sector, in alignment with targets set by the Paris Climate Agreement. Their immediate challenge is simple to state but hard to solve: "ambitious CO2 reduction objectives will only be achievable with alternative marine fuels which do not yet exist." In the long-term, however researchers recognize that "fuel cell-powered ships are likely to dominate, drawing their energy from fuels such as hydrogen and ammonia."
The American Institute of Chemical Engineers (AIChE) will present a Webinar on December 21 on "Distributed Ammonia Synthesis." The presenter will be Edward L. Cussler, Distinguished Institute Professor at the Chemical Engineering and Materials Science Department of the University of Minnesota. Distributed ammonia synthesis is one focus related to ammonia energy at the University of Minnesota - but just one. In fact, UMinn is the locus of a unique and globally significant collection of research efforts that promise to have significant impacts in the ammonia industry and the broader energy sector.
Ammonia energy proponents look forward to the day when their fuel is used in internal combustion engines – but the state of this art is unsettled and it is not clear which combustion technologies will win in the end.
Eddie Sturman, noted inventor and co-founder of Sturman Industries, has been developing ammonia internal-combustion-engine (ICE) technology for several years – "at least six, maybe more." At the 2016 NH3 Fuel Conference, he provided the most in-depth look so far at the results of Sturman Industries' R&D program. Specifically, his talk featured a dual-fuel compression ignition engine powered by a combination of diesel fuel and ammonia.
A recent paper from the University of Ontario Institute of Technology, published in June 2016, provides new data on the relative efficiency and safety of using ammonia as a transportation fuel. It presents a cradle-to-grave "comparative life cycle assessment" for a range of vehicles, encompassing the vehicle cycles (manufacturing, maintenance, and disposal) and the fuel cycle (operation).
