Site items in: Electrochemical Ammonia

Presentation

Atmospheric-Pressure Synthesis of Ammonia Using Non-Thermal Plasma with the Assistance of Ru-Based Multifunctional Catalyst

Peng Peng Yanling Cheng Nan Zhou Raymond Hatzenbeller Paul Chen Roger Ruan

Ammonia has much more uses than being a fertilizer. Its emerging applications include hydrogen carrier, fuel cells, clean transportation fuels, and other off-grid power applications. The traditional Haber Bosch process used to synthesize ammonia must be achieved at high temperature and pressure. The non-thermal plasma (NTP) allows for the synthesis of ammonia at a lower temperature and pressure conditions. It is proposed that the moderate process conditions can potentially allow a more economical construction and operation of ammonia production systems on distributed farms and renewable hydrogen production sites. In this study, we report the NTP synthesis of ammonia using dielectric…

Presentation

Nitrogenase Inspired Peptide-Functionalized Catalyst for Efficient, Emission-Free Ammonia Production

Stephen Szymanski Wayne Gellett

Ammonia-based fertilizers have enabled increases in food production to sustain the world’s population. Currently the major source of ammonia is the Haber-Bosch process, which requires high temperature and pressure and has low conversion efficiency, such that very large plants are required for economical production. Ammonia is therefore one of the most energy and carbon intensive chemical processes worldwide, largely due to the steam methane reforming step to produce the required hydrogen. Because of the very large plant scale and resulting centralization of production, ammonia may also be transported long distances to point of use, adding additional energy and emissions. Distributed,…

Presentation

Future of Ammonia Production: Improvement of Haber-Bosch Process or Electrochemical Synthesis?

Grigorii Soloveichik

Ammonia, the second most produced chemical in the world (176 million tons in 2014), is manufactured at large plants (1,000 – 1,500 t/day) using Haber-Bosch process developed more than hundred years ago. A simple reaction of nitrogen and hydrogen (produced by steam methane reforming or coal gasification) consumes about 2% of world energy, in part due to the use of high pressure and temperature. With the global transition from fossil fuels to intermittent renewable energy sources there is a need for long term storage and long range transmission of energy, for which ammonia is perfect fit. To make it practical,…

Presentation

Comprehensive Evaluation of NH3 Production and Utilization Options for Clean Energy Applications

Greg Vezina Ibrahim Dincer Yusuf Bicer

The project proposes a comprehensive investigation on the analysis, assessment and optimization of ammonia synthesis processes under renewable energy portfolio, including low-cost hydro, wind, solar, geothermal, ocean, biomass, etc. Furthermore, ammonia production via hydrocarbon decomposition, which will be investigated in the study, is a promising option to utilize fossil fuels in a cleaner and environmentally benign way. Case studies for various locations and applications in communities, cities and provinces to develop and implement clean solutions are performed. The objectives of this project include energy and exergy analyses, environmental impact assessments, thermo-economic analyses and evaluations, optimization studies, experimental investigation, scalability and…

Article

254th ACS Meeting, Energy and Fuels Symposium “The Ammonia Economy” — Synthesis, Utilization & Nitrogen Reduction

Michael Mock October 31, 2017

In late August, the day before the exciting solar eclipse, the Ammonia Economy symposium was held as part of the Energy and Fuels Division of the American Chemical Society (ACS) National Meeting in Washington DC. This marks the third gathering of Ammonia related research since 2015 at the national level ACS conference. This year, in addition to the important focus on chemistries for the utilization of ammonia, the rapidly developing field of homogeneous catalysts and biological processes for nitrogen fixation was included as a major theme.

Article

Overcoming the Selectivity Challenge in Electrochemical Ammonia Synthesis

Trevor Brown October 06, 2017

In the last 12 months ... The research community has made great progress toward solving the "selectivity challenge" in electrochemical ammonia synthesis. Although, rather than an actual solution, mostly what we have is a range of sophisticated work-arounds that succeed in making this problem moot.

Presentation

High Efficiency Electrochemical Synthesis of Ammonia from Nitrogen at Ambient Temperature and Pressure

Greg Redden Fengling Zhou Luis Azofra Muataz Ali Mega Kar Alexandr Simonov Ciaran McDonnell Chenghua Sun Angeline Bartholomeusz Xinyi Zhang Douglas MacFarlane

Ammonia as well as being an important fertiliser is being increasingly considered as an easily transported carrier of hydrogen energy. However, the traditional Haber-Bosch process for the production of ammonia from atmospheric nitrogen and fossil fuels is a high temperature and pressure process that is energy intensive. Newer technology is being investigated to produce sustainable ammonia from green energy. An ambient temperature, electrochemical synthesis of ammonia is an attractive alternative approach, but has, to date, not been achieved at high efficiency. Researchers from Monash University have obtained faradaic efficiency as high as 60% using liquid salt electrolytes under ambient conditions,…

Article

Sustainable ammonia synthesis: SUNCAT's lithium-cycling strategy

Trevor Brown July 21, 2017

New research coming out of Stanford University suggests a fascinating new direction for electrochemical ammonia synthesis technology development. The US-Danish team of scientists at SUNCAT, tasked with finding new catalysts for electrochemical ammonia production, saw that 'selectivity' posed a tremendous challenge - in other words, most of the energy used by renewable ammonia production systems went into making hydrogen instead of making ammonia. The new SUNCAT solution does not overcome this selectivity challenge. It doesn't even try. Instead, these researchers have avoided the problem completely.

Article

Electrochemical ammonia synthesis in South Korea

Trevor Brown June 09, 2017

One of the many encouraging announcements at the recent Power-to-Ammonia conference in Rotterdam was the news that the Korea Institute of Energy Research (KIER) has extended funding for its electrochemical ammonia synthesis research program by another three years, pushing the project forward through 2019. KIER's research target for 2019 is significant: to demonstrate an ammonia production rate of 1x10^-7 mol/s·cm². If the KIER team can hit this target, not only would it be ten thousand times better than their 2012 results but, according to the numbers I'll provide below, it would be the closest an electrochemical ammonia synthesis technology has come to being commercially competitive.

Article

On the Ground in Germany

Trevor Brown February 09, 2017

Yet another national laboratory is developing technology for renewable ammonia, this time in Germany at the DLR, the German Aerospace Center. At the Institute of Thermodynamic Engineering, the DLR is developing a method for electrochemical ammonia synthesis at ambient conditions.