Site items in: Emissions Testing

Presentation

Experimental and Computational Study for Reduction of NOx Emissions in the Ammonia / Methane Co-Combustion in a 10 KW Furnace

Ryuichi Murai Ryohei Omori Takahiro Kitano Hidetaka Higashino Noriaki Nakatsuka Fumiteru Akamatsu Yuya Yoshizuru Jun Hayashi

There are severe issues on increasing amount of carbon dioxide (CO2) emission in the world. Many studies are devoted to alternative fuels. One of promising candidates is the utilization of ammonia which is zero emission of CO2, a hydrogen energy carrier, and also can be burned directly as a fuel. For direct combustion of ammonia in industrial furnaces, there were two issues which were weaker radiative heat flux and a huge amount of NOx emission compared with the combustion of methane. We already have reported [1] the solution of the former issue by using the oxygen enriched combustion. The objective…

Presentation

Auto-Ignition Kinetics of Ammonia at Intermediate Temperatures and High Pressures

Xiaoyu He Bo Shu Kai Moshammer Ravi Fernandes David Nascimento Mário Costa

The anxiety over global greenhouse gas emissions has intensified the demand for the development and use of CO2-neutral energy technologies. Ammonia is now attracting attention as a carbon-free energy carrier, because it has good energy density (22.5 MJ/kg) and can be easily liquefied (about 10 bar at 298 K). In addition, ammonia is produced according to the Haber-Bosch process, which makes it one of the most widely-produced inorganic chemical in the world. It could also be produced with renewable energy sources such as wind and solar energy using P2X technology. As a potential fuel for applications in gas turbines and…

Presentation

Optimization of the NOx Reduction Condition in the Combustion Furnace for the Combustion of "Heavy-Oil - NH3 System" Using CFD

Yuya Yoshizuru Takeshi Suemasu Masayuki Nishio Ryuichi Murai Fumiteru Akamatsu

In late years the discharge of the CO2 became the very big problem. The combustion of the fossil fuel in particular exhausts much CO2. Our project team (SIP) is intended to reduce CO2 by using NH3 (10%~30%) in substitution for heavy oil. The ‘SIP energy carriers’ was launched in 2014 (SIP: Strategic Innovation Promotion Program). Ammonia direct combustion team was formed. We conducted a co-research program with Osaka University in this project. We performed experiment of heavy oil – NH3 mixed combustion in the 10kW furnace. As the results, we obtained much experimental data. When we were combusted NH3 and…

Presentation

Two Stage Ammonia Combustion in a Gas Turbine like Combustor for Simultaneous NO and Unburnt Ammonia Reductions

Akihiro Hayakawa K.D. Kunkuma A. Somarathne Masaaki Tsukamoto Taku Kudo Hideaki Kobayashi

Ammonia is expected not only as a hydrogen energy carrier but also as a carbon free fuel. Recently, ammonia fueled gas turbine combustor was successfully demonstrated. However, large amount of NOx was produced when ammonia burns because ammonia includes nitrogen atom in the ammonia molecule. In addition, unburnt ammonia concentration in exhaust gas also needs to be reduced. In this study, we proposed a combustion concept in order to reduce NO and unburnt ammonia concentrations in the exhaust gas simultaneously in a gas turbine like model swirl combustor. In this concept, two stage (rich – lean) combustion was employed. Two…

Presentation

Development of Low-NOx Combustor of Micro Gas Turbine Firing Ammonia Gas

Osamu Kurata Norihiko Iki Takahiro Inoue Takayuki Matsunuma Taku Tsujimura Hirohide Furutani Masato Kawano Keisuke Arai Ekenechukwu Chijioke Okafor Akihiro Hayakawa Hideaki Kobayashi

A massive influx of renewable energy is required in order to mitigate global warming. Although hydrogen is a renewable media, its storage and transportation in large quantity is difficult. Ammonia, however, is a hydrogen energy carrier, and its storage and transportation technology is already established. Although ammonia fuel combustion was studied in the 1960s in the USA, the development of an ammonia fuel gas turbine had been abandoned because combustion efficiency was unacceptably low [1]. Recent demand for hydrogen energy carrier revives the usage of ammonia fuel. The National Institute of Advanced Industrial Science and Technology (AIST) in Japan, in…

Presentation

Basic Co-Firing Characteristics of Ammonia with Pulverized Coal in a Single Burner Test Furnace

Akira Yamamoto Masayoshi Kimoto Yasushi Ozawa Saburo Hara

Ammonia is expected as a potential fuel to substitute fossil fuels, because it does not discharge carbon dioxide and is easily handled by liquefaction. There are several ways for the direct use of ammonia as a fuel; for example, use in fuel cells and combustion devices. One of the possible application is the combustion use in thermal power plants. In particular, co-firing of ammonia in coal-fired power plants seems to have a relatively great advantage on the suppression of greenhouse gases, because coal is one of the main emission source of carbon dioxide. On the other hand, it is concerned…

Presentation

Ammonia-Hydrogen Power for Combustion Engines

Agustin Valera-Medina Phil Bowen Daniel Pugh

Ammonia blends can potentially become a breakthrough chemical for power generation, cooling storage and distribution of energy. Gas turbines and internal combustion engines are potential candidates for the use of the resource in an efficient way that will enable commissioning of combined cycles to power communities around Europe and around the world while serving as sources of heat and chemical storage. Therefore, development of these systems will bring to the market a safer, zero carbon fuel that can be used for multiple purposes, thus decentralizing power generation and increasing sustainability in the communities of the future whilst positioning the developing…

Presentation

NH3 / N2 / O2 Non-Premixed Flame in a 10 kW Experimental Furnace – Characteristics of Radiative Heat Transfer

Ryuichi Murai Ryohei Omori Ryuki Kano Yuji Tada Hidetaka Higashino Noriaki Nakatsuka Jun Hayashi Fumiteru Akamatsu Kimio Iino Yasuyuki Yamamoto Yoshiyuki Hagiwara

There are severe issues on increasing amount of carbon dioxide (CO2) emission in the world. Many studies are devoted on alternative fuels. One of superior candidates is the utilization of hydrogen energy which can realize a low-carbon and hydrogen-based society. Ammonia might play an important role which is zero emission of CO2, and is useful for hydrogen energy carrier as a clean energy. Additionally, ammonia is an easily-liquefiable fuel with pressure of about 0.86 MPa and temperature of 293 K. Commercially, ammonia is produced in large quantity by the Haber–Bosch process. It is also to be produced by using catalyst…

Presentation

Efficient and Clean Combustion of Ammonia-Hydrogen-Air Mixtures

Hadi Nozari Arif Karabeyoğlu

Based on its well-known merits ammonia has been gaining special attention as a potential renewable energy carrier which can be replaced in power generation systems. Considering its low flame speed and its potential for producing fuel NOx as the main challenges of combusting ammonia, flame stability, combustion efficiency, and NOx formation are experimentally investigated. Focus is on premixed ammonia-hydrogen-air flames with high mixture fractions of ammonia (60-90% by volume) under standard temperature and pressure conditions. We introduce silicon-carbide (SiC) porous block as a practical and effective medium for ammonia-hydrogen-air flame stabilization which enables stable and efficient combustion of the mixtures…

Presentation

Effects of the Thickness of the Burner Rim, the Velocities of Fuel and Air on Extinction Limit of Ammonia Coaxial Jet Diffusion Flame

Yohei Ishikawa Jun Hayashi Hiroyuki Takeishi Takahiro Okanami Kimio Iino Fumiteru Akamatsu Yasuyuki Yamamoto Yoshiyuki Hagiwara

Ammonia is regarded as one of the alternative fuels because CO2 doesn’t emit during the combustion process of ammonia. Ammonia also has advantages in storage and transportation. In addition, ammonia has a potential to be a “hydrogen carrier” because of high amount of hydrogen content. However, there are several combustion related problems such as the low flammability, the low radiative power and the high NOx formation. To use ammonia as a fuel, therefore, it is necessary to understand the fundamental phenomena of the combustibility of the ammonia such as laminar burning velocity, strength of the radiation and extinction limit. Since…