Site items in: Energy Carrier

On the Ground in Japan: FCV Uptake and Hydrogen Fueling Stations
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Module four of the ten-module research and development agenda for Japan’s Cross-Ministerial Strategic Innovation Promotion Program -- Energy Carriers is entitled “Basic Technology for Hydrogen Station Utilizing Ammonia.” The rationale for including this technology is that “high purity H2 supply system with low cost hydrogen transportation is a key issue to spread fuel cell vehicles (FCVs).” A story published last week in the Tokyo Shimbun says that to date FCVs have not spread very far. Among the factors seen as constraints is the cost of hydrogen fueling stations (HFS). The Tokyo Shimbun story states that “according to industry officials, each station that supplies hydrogen to fuel cell vehicles runs about ¥400 million ($3.6 million) in construction costs. In order to achieve profitability, about 1,000 fuel cell vehicles are required as customers per location. Construction is not proceeding.” So far, the players focused on FCVs do not seem to be looking to ammonia as an expedient that will help reduce the cost of HFS and thereby encourage their construction and by extension the uptake of FCVs. This appears to be a missed opportunity whose benefits may become too compelling to ignore.

CSIRO Membrane: Ammonia to High-Purity Hydrogen
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In Australia this week, CSIRO announced funding for the "final stages of development" of its metal membrane technology to produce high-purity hydrogen from ammonia. The two year research project aims to get the technology "ready for commercial deployment," with industrial partners including Toyota and Hyundai.

The Hydrogen Consensus
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Let’s say there is such a thing as the “hydrogen consensus.” Most fundamentally, the consensus holds that hydrogen will be at the center of the sustainable energy economy of the future. By definition, hydrogen from fossil fuels will be off the table. Hydrogen from biomass will be on the table but the amount that can be derived sustainably will be limited by finite resources like land and water. This will leave a yawning gap (in the U.S., 60-70% of total energy consumption) that will be filled with the major renewables -- wind, solar, and geothermal -- and nuclear energy. This may be as far as the consensus goes today, but more detail is now emerging on the global system of production and use that could animate a hydrogen economy.

On the Ground in Japan: LH2 and MCH Hydrogen Fueling Stations
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While Japan’s Cross-Ministerial Strategic Innovation Promotion Program (SIP) continues to evaluate liquid hydrogen (LH2), methylcyclohexane (MCH), and ammonia as hydrogen energy carriers, Japanese press reports show that the backers of liquid hydrogen and MCH are building an early lead over ammonia with hydrogen fueling stations based on their favored commodities.

New Technology for Generating Hydrogen from Ammonia
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On March 21, Gifu University in Japan announced a breakthrough in technology for generating hydrogen from ammonia. A press release from the Gifu Prefectural Association Press Club stated that Professor Shinji Kambara, Director of the Next Generation Research Center within the Environmental Energy Systems Department at the Gifu University Graduate School of Engineering, has developed a "plasma membrane reactor" that is capable of evolving hydrogen with a purity of 99.999 percent from an ammonia feedstock. This surpasses the 99.97 percent purity announced last July by a research group centered at Hiroshima University with a hydrogen generation device based on a different technology.

Bunker Ammonia: carbon-free liquid fuel for ships
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The shipping industry is beginning to evaluate ammonia as a potential "bunker fuel," a carbon-free alternative to the heavy fuel oil (HFO) used in maritime transport. International trade associations are leading the effort to decarbonize the sector, in alignment with targets set by the Paris Climate Agreement. Their immediate challenge is simple to state but hard to solve: "ambitious CO2 reduction objectives will only be achievable with alternative marine fuels which do not yet exist." In the long-term, however researchers recognize that "fuel cell-powered ships are likely to dominate, drawing their energy from fuels such as hydrogen and ammonia."

Ammonia for energy storage: economic and technical analysis
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Developers around the world are looking at using ammonia as a form of energy storage, essentially turning an ammonia storage tank into a very large chemical battery. In the UK, Siemens is building an "all electric ammonia synthesis and energy storage system." In the Netherlands, Nuon is studying the feasibility of using Power-to-Ammonia "to convert high amounts of excess renewable power into ammonia, store it and burn it when renewable power supply is insufficient." While results from Siemens could be available in 2018, it might be 2021 before we see results from Nuon, whose "demonstration facility is planned to be completed in five years." But, while we wait for these real-world industrial data, the academic literature has just been updated with a significant new study on the design and performance of a grid-scale ammonia energy storage system.

On the Ground in Japan
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Two talks delivered in December show the tiny steps that allow a country to transition to a sustainable energy economy. The country is Japan. The events hosting the talks were short-format symposia whose evident objective was to draw in business and technical people who might become practically involved in the new energy economy. Both talks highlighted the role to be played by ammonia while also describing competing and complementary technologies.

Hydrogen Fueling Station Development in Japan
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Two announcements – focused on very different approaches for supplying hydrogen as a transportation fuel – shine a light on Japan’s approach to creating a national hydrogen energy economy. On January 24, the American company Air Products and Chemicals, Inc. issued a press release about the launch of the Shikaoi Hydrogen Farm fueling station in Hokkaido, Japan. The station will be supplied by hydrogen derived from agricultural wastes via anaerobic digestion and Air Products’ biogas purification and steam methane reforming (SMR) technologies. The project was undertaken by a consortium that includes the Japanese companies Nippon Steel and Sumikin Pipeline & Engineering, Air Water, Inc., and Kajima Corporation. Six months earlier, on July 19, 2016, the Japan Science and Technology Agency (JST) announced that another consortium – this one led by Hiroshima University and including Showa Denko, Taiyo Nichi Company, and Toyota Industries – had succeeded in developing “viable technology to produce high-purity hydrogen [from an] ammonia hydrogen station.”

Hydrogen Council - new global initiative launched at Davos
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This week, at the World Economic Forum in Davos, the leaders of 13 global companies, representing more than EUR 1 trillion in annual revenues, announced the launch of the Hydrogen Council. This new global initiative is important for obvious reasons: it presents a compelling "united vision and long-term ambition" for hydrogen, it promises global engagement with "key stakeholders such as policy makers, business and hydrogen players, international agencies and civil society," and it pledges financial commitments to RD&D totaling EUR 10 billion over the next five years. It is important for a subtler reason too: it is the first hydrogen industry promotion I've seen that includes ammonia. It includes ammonia both implicitly, encompassing "hydrogen and its compounds," and explicitly, listing ammonia as a "renewable fuel" in its own right.