Ammonia absorber columns offer an alternative separation unit to replace condensation in the Haber-Bosch synthesis loop. Metal halide salts can selectively separate ammonia from the reactor outlet gas mixture and incorporate it into their crystal lattice with remarkably high thermodynamic capacity. While the salts’ working capacity can be limited and unstable when they are in their pure form, the capacity is stable and can be high when using a porous silica support. Here, we discuss optimal conditions for uptake and release of ammonia. The production capacity (ammonia processed per unit absorbent and per unit production time) depends on processing parameters…
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Optimizing Absorptive Separation for Intensification of Ammonia Production
High pressure requirements of Haber-Bosch process imposes substantial operating (e.g., compression) and capital (compressor cost, advanced costly alloys, thick reactor casing, etc.) expenses in the ammonia production. Cost considerations force ammonia producers to take advantage of the economy of scale to drive down the manufacture cost, while small and energy-efficient processes that can be powered with off-grid renewable energy are required for ammonia-mediated hydrogen economy. Small-scale reaction-absorption process is proposed to be a viable technology to reduce the operating pressure requirements of Haber-Bosch process.1–4 Here, we present an overview of our efforts to further intensify ammonia production via reaction-absorption process.…
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NH3 emulsions in internal combustion engines
NH3 emulsions in internal combustion engines Shehan Haputhanthri, Texas Tech University
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Ammonia as an alternate transport fuel: Emulsifiers for gasoline ammonia fuel blends and real time engine performance
Ammonia is a carbon-free solution to energy crisis without strenuous changes to the existing infrastructure. Ammonia and hydrocarbon liquid fuel blends can be used to power existing IC engines as an alternative transportation fuel. Due to the structure of ammonia and hydrocarbon molecules an emulsifying agent has to be used to obtain a stable and high molality solution. Feasibility of ammonia and gasoline liquid fuel blends using ethanol and methanol as emulsifiers was studied in this research. A small thermo-stated vapor liquid equilibrium (VLE) high pressure cell was used to study the solubility of ammonia in gasoline. A larger VLE…