University of Minnesota

Ahead of the 3rd Symposium on Ammonia Energy in Shanghai next month, we take the opportunity to highlight select papers and key results from the first two editions, starting with the 2022 Cardiff event:

• In an ammonia-diesel blending study, Orleans University and WinGD found that minimising the diesel fraction actually led to increased N₂O emissions.
• In a bid to produce an optimal ammonia-hydrogen fuel blend, a University of Birmingham team characterised the ammonia cracking mechanism of a new, transition metal-promoted lithium amide catalyst.
• A KAUST study of swirl intensity of an ammonia-methane blended fuel finds that increasing the swirl number leads to a more compact flame, reducing NO_X emissions.
• A team from the University of Minnesota found that combustion durations comparable to gasoline were obtained for ammonia-hydrogen fuel blends.
• And, as part of a joint academic-industry session on safety, it was recommended that a careful, proactive approach is taken towards new ammonia users, likely exposure risk points and deploying maritime ammonia fuel.

A team led by the Norwegian University of Science and Technology (NTNU) and the Silesian University of Technology (SUT) is currently working on Project ACTIVATE. Their goal is to field demonstrate an ammonia-powered, cost-competitive agricultural vehicle by late 2023.

Last week we presented the first episode in our monthly webinar series: Ammonia Energy Live. Every month we’ll explore the wonderful world of ammonia energy and the role it will play in global decarbonisation - with an Australian twist. To kick things off we wanted to set the scene for 2021 and give you a sense of where the ammonia transition is at - key projects, key milestones and things to be excited about going forward. And, since this is an Australian-focused series, we wanted to explore what’s important about Australia to the ongoing work of the AEA.

This year's ammonia conference in Rotterdam, the third annual NH3 Event, begins two weeks from today. Since our guest post in March, announcing the initial roster of conference speakers, the organizers have confirmed new speakers, added more sessions, and announced further details. The NH3 Event is a two-day conference, taking place on June 6 & 7, presenting "state of the art solutions and innovations on the subject of Sustainable Ammonia." Although the conference hall is already close to capacity, a few dozen tickets remain available through the NH3 Event website.

At the 2017 NH3 Energy+ Conference, graduate student Doga Demirhan reported on an ongoing investigation at the Energy Institute at Texas A&M University. The work involved evaluation of options for an ammonia production system and concluded that biomass could be an economically viable feedstock under current, real-world conditions. This is a notable outcome. Just as notable is how it was reached.

At the recent NH3 Energy+ Topical Conference, Grigorii Soloveichik described the future of ammonia synthesis technologies as a two-way choice: Improvement of Haber-Bosch or Electrochemical Synthesis. Two such Haber-Bosch improvement projects, which received ARPA-E-funding under Soloveichik's program direction, also presented papers at the conference. They each take different approaches to the same problem: how to adapt the high-pressure, high-temperature, constant-state Haber-Bosch process to small-scale, intermittent renewable power inputs. One uses adsorption, the other uses absorption, but both remove ammonia from the synthesis loop, avoiding one of Haber-Bosch's major limiting factors: separation of the product ammonia.

In late August, the day before the exciting solar eclipse, the Ammonia Economy symposium was held as part of the Energy and Fuels Division of the American Chemical Society (ACS) National Meeting in Washington DC. This marks the third gathering of Ammonia related research since 2015 at the national level ACS conference. This year, in addition to the important focus on chemistries for the utilization of ammonia, the rapidly developing field of homogeneous catalysts and biological processes for nitrogen fixation was included as a major theme.

Last week, ARPA-E announced funding for eight technologies that aim to make ammonia from renewable electricity, air, and water. The technological pathways being developed include adaptations of the Haber-Bosch process - seeking improvements in catalysts and absorbents - as well as novel electrochemical processes.

NH3 Fuel Association President Norm Olson presented his paper “NH3 – the Optimal Liquid Transportation Fuel” on November 9 at the annual meeting of the American Institute of Chemical Engineers (AIChE). The AIChE meeting, held over six days in San Francisco, provided a wide-ranging perspective on the sustainable energy landscape that ammonia energy must compete within.

The team at the University of Minnesota announced last month the award of funding for a demonstration project entitled "Clean Vehicles Fueled by Hydrogen from Renewable Ammonia." This project builds on years of research and investment in renewable ammonia at University of Minnesota, most visibly the prototype wind-to-ammonia production plant operating since 2014 at West Central Research and Outreach Center. Their focus now, however, is shifting to the use of ammonia as a fuel. "The overall objective of the project is to displace up to 50% of the diesel fuel used in tractors with anhydrous ammonia produced from renewable resources."