Optimizing absorption to improve Haber-Bosch synthesis

Presented on November 11, 2021 during the Ammonia Energy Conference 2021

Authors Alon McCormick Matthew Kale Cory Marquart Deepak Ojha Chinomso Emmanuel Onuoha Matthew Palys Zac Pursell Edward Cussler Prodromos Daoutidis Paul Dauenhauer Michael Reese University of Minnesota

Download this Presentation Download a PDF version of this presentation.

Abstract

Ammonia absorber columns offer an alternative separation unit to replace condensation in the Haber-Bosch synthesis loop. Metal halide salts can selectively separate ammonia from the reactor outlet gas mixture and incorporate it into their crystal lattice with remarkably high thermodynamic capacity. While the salts’ working capacity can be limited and unstable when they are in their pure form, the capacity is stable and can be high when using a porous silica support.

Here, we discuss optimal conditions for uptake and release of ammonia. The production capacity (ammonia processed per unit absorbent and per unit production time) depends on processing parameters – including uptake and regeneration temperatures, ammonia partial pressures, release time, and sweep gas flow rate. Moreover, attention should be paid to balancing the release time with the full cycle time and bed size to ensure that the uptake breakthrough time makes efficient use of the bed. These parameters are mutually interdependent, so their optimization can be nontrivial, but rewarding.

To address this challenge and to allow a large set of experiments, an automated dynamic absorption system was designed, fabricated, and used to rapidly screen uptake and release conditions, to assess material stability, and to identify optimal cycling conditions. The large amount of experimental data obtained from this automated system, and the associated mathematical models validated by this data, were found to be an essential tool to optimize the design of the absorber column. In turn, this task is essential to assess improvement in the techno-economic prospects for this new separation approach.

We also share some of our findings regarding the scaleup. These indicate potential processing challenges that need attention in design (de-risking) to ensure optimal operation in bench-scale and production-scale units.

Topics Distributed ammonia synthesis Improved Haber-Bosch

Authors mccormic@umn.edu kalemj11@gmail.com Cory Marquart Deepak.Ojha palys003@umn.edu Chinomso.Onuoha Zac.Pursell cussler@umn.edu daout001@umn.edu hauer@umn.edu reesem@umn.edu Sameer.Parvathikar mahdi.malmali@ttu.edu

IMO Webinar

Please join us for this informative webinar. Click here to register and get the details!

Annual Conference Presentations available

Presentations from the AEA Annual Conference are now available on the website. The presentations are organized by session and speaker within the conference schedule for your convenience.

2023 Annual Report

In 2023, AEA reached many milestones. Read about them in our 2023 Annual Report.