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Presentation

Development of Materials and Systems for Ammonia-Fueled Solid Oxide Fuel Cells

Koichi Eguchi Yosuke Takahashi Hayahide Yamasaki Hidehito Kubo Akihiro Okabe Takenori Isomura Takahiro Matsuo

Hydrogen is the primary fuel source for fuel cells. However, the low volume density and difficulty in storage and transportation are major obstacles for the practical utilization. On-site generation of hydrogen from its carrier is an effective method for the fuel supply. Among various hydrogen carriers, ammonia is one of the promising candidates. Ammonia has high hydrogen density. The boiling point of ammonia is relatively high, leading to the ease in liquefaction and transportation. Hydrogen can be produced from ammonia with a mildly endothermic process. The reaction temperature of ammonia cracking is about 600˚C or higher which is close to…

Presentation

Detailed Observation of Coal-Ammonia Co-Combustion Processes

Noriaki Nakatsuka Junpei Fukui Kazuki Tainaka Hidetaka Higashino Jun Hayashi Fumiteru Akamatsu

Coal-fired power generation is supplying about 30% of the world’s primary energy. Almost all of coal-fired power plants in Japan employ the pulverized coal combustion method. In the pulverized coal combustion, coal is pulverized into a powder of several tens of microns. This method enables to burn coal effectively because of the large surface to volume ratio. Pulverized coal particles are supplied to the actual boilers with primary air whose Air/Coal ratio (mass flow rate of primary air/mass flow rate of pulverized coal) is set to 2.0. Co-combustion of coal with ammonia has been studied with the aim of reducing…

Presentation

Combustion Emissions from NH3 Fuel Gas Turbine Power Generation Demonstrated

Osamu Kurata Norihiko Iki Takahiro Inoue Takayuki Matsunuma Taku Tsujimura Hirohide Furutani Hideaki Kobayashi Akihiro Hayakawa

To protect against global warming, a massive influx of renewable energy is expected. Although H2 is a renewable media, its storage and transportation in large quantity is difficult. NH3 fuel, however, is an H2 energy carrier and carbon-free fuel, and its storage and transportation technology is already established. Although NH3 fuel combustion was studied in the 1960s in the USA, the development of an NH3 fuel gas turbine had been abandoned because combustion efficiency was unacceptably low [1]. Recent demand for H2 energy carrier revives the usage of NH3 fuel, but no one has attempted an actual design setup for…

Presentation

The Role of "Green" Ammonia in Decarbonising Energy Systems: Practical Demonstration and Economic Considerations

Ian Wilkinson

Ammonia has the potential to contribute significantly to the decarbonisation of energy systems, by offering a practical, carbon-free hydrogen storage and transportation vector as well as a green fuel in its own right. To better understand the prospects and challenges surrounding the use of ammonia in energy systems, Siemens is leading a collaborative project to build and test an ammonia-based energy storage system at the Rutherford Appleton Laboratory in the UK. Together with its project partners (the UK Science and Technology Facilities Council, the University of Oxford and the University of Cardiff), and supported by Innovate UK, Siemens will demonstrate…

Presentation

Comprehensive Evaluation of NH3 Production and Utilization Options for Clean Energy Applications

Greg Vezina Ibrahim Dincer Yusuf Bicer

The project proposes a comprehensive investigation on the analysis, assessment and optimization of ammonia synthesis processes under renewable energy portfolio, including low-cost hydro, wind, solar, geothermal, ocean, biomass, etc. Furthermore, ammonia production via hydrocarbon decomposition, which will be investigated in the study, is a promising option to utilize fossil fuels in a cleaner and environmentally benign way. Case studies for various locations and applications in communities, cities and provinces to develop and implement clean solutions are performed. The objectives of this project include energy and exergy analyses, environmental impact assessments, thermo-economic analyses and evaluations, optimization studies, experimental investigation, scalability and…

Presentation

Ammonia Renewable Energy Fuel Systems at Continental Scale

William Leighty

We must soon “run the world on renewables” but cannot, and should not try to, accomplish this entirely with electricity transmission. New, abundant, low-cost, unconventional natural gas supplies are finite; burning adds CO2 to Earth’s atmosphere. Humanity’s goal must be nothing less than: Transforming the world’s largest industry from ~80% fossil to ~100% renewable, CO2-emission-free energy sources as quickly as we prudently and profitably can. We should now carefully consider using pipeline networks, rather than the electricity grid, for solving the three salient technical problems of renewable energy (RE) at lower cost: Transmission: from diverse, stranded, remote, rich RE resources…

Presentation

Ammonia Fuel Safety

Trevor Brown

This paper introduces the existing literature on the safety of using ammonia as a fuel, which provides comparative data for a range of traditional and alternative fuels and energy carriers. The studies reviewed conclude that risk levels associated with using ammonia as a fuel are “similar to those of gasoline,” or “similar, if not lower than for the other fuels,” also including hydrogen, methanol, LPG, and CNG. Ammonia as a fuel can meet all “acceptable” risk levels in even the most stringent regulatory jurisdictions. Addressing popular misconceptions and fears by providing robust sources for quantitative data on the dangers of…

Presentation

Nitrogen-Based Fuels: Renewable Hydrogen Carriers

Gideon S. Grader Michael Epstein Ayillath Deepa Oren Elishav Gennady E. Shter Bar Mosevitzky

Renewable energy sources such as solar and wind suffer from an intermittent power output, making energy storage a key element in future energy infrastructure. Fuels offer both high energy densities and efficient transport compared to other energy storage alternatives. One energy storage solution is water electrolysis. However, the generated hydrogen is incompatible with the global fuel infrastructure, inhibiting its implementation as an energy vector. Storing hydrogen on carrier atoms provides a safe and convenient way to utilize and transport renewable energies. While carbon–based fuels are commonly suggested, using nitrogen as a hydrogen carrier can potentially offer a superior option. In…

Presentation

Dutch Initiatives to Store Sustainable Energy in the Form of Ammonia

Hans Vrijenhoef

Proton Ventures BV is a company dedicated to supply mini ammonia units for storing decentralised produced (sustainable) energy. Proton has developed a commercial unit for the production of small amounts of ammonia, which can store up to 25 MW of power or equivalent (bio-) gas energy. Hans Vrijenhoef, as the director of the company, will give an overview of existing plans in The Netherlands to store this decentralised energy and to make use of this in an economic way. The N-Fuel units will be skid-mounted, safe in operation, and almost fully automated in order to keep CAPEX and OPEX costs…

Presentation

NH3: The Optimal Alternative Fuel (2017)

Julian Atchison

Unlike some technology areas where “all of the above” has significant advantages, there are tremendous advantages associated with choosing a single, optimized, liquid transportation fuel. The cost, efficiency and environmental benefits associated with choosing an optimized liquid transportation fuel are enormous and merit serious consideration. NH3 most closely meets the criteria for an ideal liquid transportation fuel. It is the most efficient and cost-effective means of delivering hydrogen and has an extensive world-wide delivery system already in place. Using currently available catalytic controls, NH3 emissions can be even cleaner than hydrogen engine emissions. While NH3 can effectively be produced using…